SYNTHESIS, CRYSTAL STRUCTURE AND THERMAL STUDIES OF TRIPHENYLSILANOL-PIPERAZINE ADDUCT

Dinesh, M. and Kavitha, V. and Prabusankar, G. and Babu, B. and babu, B. Mohan and Donghui, G. and Maadeswaran, P. (2020) SYNTHESIS, CRYSTAL STRUCTURE AND THERMAL STUDIES OF TRIPHENYLSILANOL-PIPERAZINE ADDUCT. Rasayan Journal of Chemistry, 13 (04). pp. 2294-2301. ISSN 09741496

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Abstract

The solid-state structure of triphenylsilanol-piperazine adduct was reported from optimized reaction conditions. The molecular composition was further supported by elemental analysis, FT-IR, multinuclear NMR (1H and13C) and TGA. In solid-state, the four triphenylsilanols are associated in tetrameric form with one piperazine molecule through intra and intermolecular hydrogen bonds that lead to the new type of hydrogen bonding. The molecule represents one of the rare examples of triphenylsilanol-amine derivatives with a new hydrogen-bonding pattern.

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IITH Creators:
IITH CreatorsORCiD
Prabusankar, G.UNSPECIFIED
Item Type: Article
Uncontrolled Keywords: Co-crystal; Crystal Structure; Hydrogen bond; Organosilicon; Piperazine; Triphenylsilanol
Subjects: Chemistry
Chemistry > Inorganic chemistry
Chemistry > Organic chemistry
Divisions: Department of Chemistry
Depositing User: . LibTrainee 2021
Date Deposited: 21 Jun 2021 10:48
Last Modified: 21 Jun 2021 10:48
URI: http://raiith.iith.ac.in/id/eprint/7963
Publisher URL: http://doi.org/10.31788/RJC.2020.1345643
OA policy: https://iith.irins.org/profile/62213
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