Structural and magnetic properties of Ba and Sn co-substituted bismuth ferrite

Durga Rao, T. and Mishra, Arpita and Sattibabu, Bhumireddi and Banerjee, Krishnarjuna and Asthana, Saket and Satya Narayana Murthy, V. and Arout Chelvane, J. (2020) Structural and magnetic properties of Ba and Sn co-substituted bismuth ferrite. In: 2nd International Conference on Recent Trends in Metallurgy, Materials Science and Manufacturing, IMME, 27-28 December 2019, Tamil Nadu; India.

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Abstract

BiFeO3(BFO) and Bi0.90Ba0.10Fe1-xSnxO3(x = 0, 0.01 and x = 0.03) compounds were synthesized by conventional solid-state route. X-ray diffraction (XRD) patterns demonstrated that the compounds crystalized in rhombohedral structure with R3c (IUCr No. 161) space group. The XRD patterns and Fourier transformation infrared spectra evidenced that the crystal structure was distorted due to the substitutions. The magnetic properties of the compounds were greatly influenced by the substitution of Ba and Sn elements at their respective sites. The appearance of weak ferromagnetism with significant remnant magnetization and improved coercive field compared to that of BFO could be ascribed to suppression of spiral modulated spin structure. Higher breakdown voltages were observed in the substituted compounds from the polarization measurements.

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IITH Creators:
IITH CreatorsORCiD
Asthana, Sakethttp://orcid.org/0000-0002-6420-3304
Item Type: Conference or Workshop Item (Paper)
Uncontrolled Keywords: Anti-ferromagnetism, Leakage current, Multiferroics, Oxygen vacancy
Subjects: Physics > Mechanical and aerospace
Physics
Physics > Classical mechanics
Physics > Fluid mechanics
Physics > Electricity and electronics
Physics > Magnetism
Physics > Modern physics
Physics > Astronomy Astrophysics
Divisions: Department of Physics
Depositing User: . LibTrainee 2021
Date Deposited: 27 May 2021 05:53
Last Modified: 27 May 2021 05:53
URI: http://raiith.iith.ac.in/id/eprint/7842
Publisher URL: http://doi.org/10.1016/j.matpr.2020.05.466
OA policy: https://v2.sherpa.ac.uk/id/publication/31455
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