Aluminium complex–catalysed hydroboration of alkenes and alkynes

Panda, Tarun K and A, Harinath and Banerjee, Indrani and Bhattacharjee, Jayeeta (2019) Aluminium complex–catalysed hydroboration of alkenes and alkynes. New Journal of Chemistry. ISSN 1144-0546 (In Press)

Full text not available from this repository. (Request a copy)


We demonstrate an efficient method for the hydroboration of terminal alkenes or alkynes with pinacolborane (HBpin) using the aluminium catalyst, [κ2-(Ph2P(=Se)NCH2(C5H4N)Al(CH3)2] (1), supported by a functionalized amidophosphine ligand under mild and solvent-free conditions to afford corresponding alkyl and alkenyl boronate esters in high yield. This protocol involves the chemoselective formation of an anti-Markovnikov product exclusively. Both terminal alkenes and alkynes bearing a wide array of electron-withdrawing as well as donating functional groups can easily be converted to the corresponding product through the formation of aluminum hydride as an active catalytic species.

[error in script]
IITH Creators:
IITH CreatorsORCiD
Panda, Tarun K
Item Type: Article
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 11 Jun 2019 10:51
Last Modified: 11 Jun 2019 10:51
Publisher URL:
OA policy:
Related URLs:

Actions (login required)

View Item View Item
Statistics for RAIITH ePrint 5456 Statistics for this ePrint Item