Synthesis and Crystal Structure of Cs2 U2 (P2 Se9 )(Se2 )2

Mesbah, Adel and Jai, Prakash and Beard, Jessica C and Lebègue, Sébastien and Ibers, James A (2018) Synthesis and Crystal Structure of Cs2 U2 (P2 Se9 )(Se2 )2. Journal of Inorganic and General Chemistry, 644 (22). pp. 1480-1484. ISSN 0044-2313

Full text not available from this repository. (Request a copy)


Black single crystals of Cs2U2(P2Se9)(Se2)2 were synthesized at 1023 K by a solid‐state reaction. Its structure was determined by single‐crystal X‐ray diffraction methods. The compound is isostructural with Rb2U2(P2Se9)(Se2)2 and Cs2Th2(P2Se9)(Se2)2 compounds, and crystallizes in the orthorhombic space group Pbca. Cs2U2(P2Se9)(Se2)2 displays a three‐dimensional structure comprising USe9 polyhedra connected via the Se22– and P2Se9 species with channels filled by Cs atoms. From electronic structure calculations the compound is found to be a metal with a ferromagnetic arrangement of the magnetic moments.

[error in script]
IITH Creators:
IITH CreatorsORCiD
Item Type: Article
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 08 Jan 2019 10:41
Last Modified: 08 Jan 2019 10:41
Publisher URL:
Related URLs:

Actions (login required)

View Item View Item
Statistics for RAIITH ePrint 4678 Statistics for this ePrint Item