Iron promoted C3–H nitration of 2H-indazole: direct access to 3-nitro-2H-indazoles

Murugan, Arumugavel and Gorantla, Koteswar Rao and Mallik, Bhabani Shankar and D S, Sharada (2018) Iron promoted C3–H nitration of 2H-indazole: direct access to 3-nitro-2H-indazoles. Organic and Biomolecular Chemistry, 16 (28). pp. 5113-5118. ISSN 1477-0520

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An efficient C3–H functionalization of indazole has been demonstrated. Notably, this method involves chelation-free radical C–H nitration on 2 H -indazole. The radical mechanism was confirmed by control experiments and quantum chemical calculations. The synthetic utility has been proven by the synthesis of bio-relevant benzimidazoindazoles via reductive cyclization.

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IITH Creators:
IITH CreatorsORCiD
Mallik, Bhabani Shankar
Item Type: Article
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 30 Jul 2018 04:09
Last Modified: 30 Jul 2018 04:09
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