Femtosecond to Microsecond Dynamics of Soret-Band Excited Corroles

Raavi, Sai Santosh Kumar and Yin, J and Grancini, G and Soci, C and Rao, S v and Lanzani, G and Giribabu, L (2015) Femtosecond to Microsecond Dynamics of Soret-Band Excited Corroles. Journal of Physical Chemistry C. pp. 1-40. ISSN 1932-7447

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We present a comprehensive photophysical investigation on a series of three corroles (TTC, P-TTC, Ge-TTC dissolved in toluene), employing femtosecond and nanosecond transient absorption spectroscopy (TAS) measurements. Systematic analyses of the TAS data determined the rates and corresponding time constants of photophysical processes: internal conversion (τIC) in the 898−525 fs range, vibrational relaxation (τ_VR) in the 7.44−13.6 ps range, intersystem crossing (τISC ) in the 033−1.09 ns range and triplet lifetime (τ_triplet) in the 0.8−3.5μs range. The estimated triplet quantum yields (ΦTriplet) were in the 0.42 − 0.61 range. Comparatively, GeTTC displayed faster τIC and higher(ΦTriplet). Additionally, the time-dependent density functional theory (DFT) calculations were performed for the three molecules. The HOMO/LUMO energy levels and the oscillator strengths of various transitions were determined and presented.

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IITH Creators:
IITH CreatorsORCiD
Raavi, Sai Santosh Kumarhttp://orcid.org/0000-0002-2496-9233
Item Type: Article
Subjects: Physics
Divisions: Department of Physics
Depositing User: Team Library
Date Deposited: 14 Dec 2015 09:43
Last Modified: 11 Sep 2017 06:58
URI: http://raiith.iith.ac.in/id/eprint/2076
Publisher URL: https://doi.org/10.1021/acs.jpcc.5b08235
OA policy: http://www.sherpa.ac.uk/romeo/issn/1089-5639/
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