Two step, one-pot sequential synthesis of functionalized hybrid polyheterocyclic scaffolds via a solid state melt reaction (SSMR)

Bakthadoss, Manickam and Srinivasan, Jayakumar and Sharada, D S and et al, . (2019) Two step, one-pot sequential synthesis of functionalized hybrid polyheterocyclic scaffolds via a solid state melt reaction (SSMR). RSC Advances, 9 (42). pp. 24314-24318. ISSN 2046-2069

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Abstract

A new one pot assembly of highly functionalized benzo[a]phenazinone fused chromene/bicyclic scaffolds via a domino Knoevenagel intramolecular hetero-Diels-Alder (IMHDA) strategy using a solid state melt reaction (SSMR) of 2-hydroxynaphthalene 1,4-dione, o-phenylenediamine, O-allyl salicylaldehyde/O-vinyl salicylaldehyde derivatives is reported. The formation of five new bonds (two C-C bonds and three C-O bonds), three six-membered rings, and three stereogenic centers in a one-pot manner is very attractive. Ease of reaction with short time, good yields with water as the only byproduct and work up free procedure are some of the excellent features of the present protocol.

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IITH Creators:
IITH CreatorsORCiD
Sharada, D SUNSPECIFIED
Item Type: Article
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 19 Aug 2019 09:29
Last Modified: 19 Aug 2019 09:29
URI: http://raiith.iith.ac.in/id/eprint/5950
Publisher URL: http://doi.org/10.1039/c9ra02590a
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