The First Monomeric β-Diketiminate Stabilized Four-Coordinated Bismuth(III) Bistrifluoromethanesulfonate

Paladugu, S and Arruri, S and G, Prabusankar and Olivier, H and Stephane, G (2012) The First Monomeric β-Diketiminate Stabilized Four-Coordinated Bismuth(III) Bistrifluoromethanesulfonate. Journal of Inorganic and General Chemistry, 638 (3-4). pp. 617-620. ISSN 0044-2313

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Abstract

The sterically encumbered β-diketiminate bismuth(III) bistriflate, LBi(OSO2CF3)2 [L = HC{(CMe)N(2, 6-iPr2C6H3)}2] (2) was prepared from a facile one-pot reaction between potassium β-diketiminate LK (1) and bismuth(III) triflate. It was characterized by elemental analysis, FT-IR, 1H NMR,13C NMR, and 19F NMR spectroscopy. The molecular structure of 2 was further confirmed by single-crystal X-ray crystallography. The solid-state structure of 2 reveals a first structurally characterized monomeric β-diketiminate supported group 15 bistriflate. The coordination number of bismuth is four.

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IITH Creators:
IITH CreatorsORCiD
G, Prabusankarhttp://orcid.org/0000-0003-1772-135X
Item Type: Article
Additional Information: We gratefully acknowledge Dr. Olivier Hernandez and Dr. Stéphane Golhen for structural refinement. We are indebted to Dr. Suresh Babu Kalidindi and Mr. Adinarayana Doddi for FT-IR measurement.
Uncontrolled Keywords: Bismuth; β-Diketiminate; Metal triflate; Main-group chemistry
Subjects: Chemistry > Inorganic chemistry
Divisions: Department of Chemistry
Depositing User: Mr. Siva Shankar K
Date Deposited: 24 Sep 2014 04:53
Last Modified: 12 Sep 2017 06:35
URI: http://raiith.iith.ac.in/id/eprint/54
Publisher URL: https://doi.org/10.1002/zaac.201100463
OA policy: http://www.sherpa.ac.uk/romeo/issn/0044-2313/
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