KOt Bu-Mediated Domino Isomerization and Functionalization of Aromatic Allylic Alcohols

Suchand, B and G, Satyanarayana (2017) KOt Bu-Mediated Domino Isomerization and Functionalization of Aromatic Allylic Alcohols. European Journal of Organic Chemistry, 2017 (26). pp. 3886-3895. ISSN 1434-193X (In Press)

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Transition-metal- as well as ligand-free base-mediated domino isomerization and alkylation of allylic alcohols is presented. This protocol features the conversion of simple allylic alcohols into the corresponding ketones through isomerization in the presence of a simple base. Significantly, these in situ generated ketones subsequently undergo alkylation with styrenes as electrophiles, in a domino one-pot fashion, as an atom- and step-economical chemical process.

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IITH Creators:
IITH CreatorsORCiD
G, SatyanarayanaUNSPECIFIED
Item Type: Article
Uncontrolled Keywords: Isomerization; Allylic compounds; Ketones; Domino reactions; Hydrogen transfer
Subjects: Chemistry > Organic chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 21 Jul 2017 05:06
Last Modified: 21 Jul 2017 05:06
URI: http://raiith.iith.ac.in/id/eprint/3412
Publisher URL: https://doi.org/10.1002/ejoc.201700440
OA policy: http://www.sherpa.ac.uk/romeo/issn/1434-193X/
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