Selenium/Graphite Platelet Nanofiber Composite for Durable Li–Se Batteries

Mukkabla, R and Deshagani, S and Meduri, P and M, Deepa and Ghosal, P (2017) Selenium/Graphite Platelet Nanofiber Composite for Durable Li–Se Batteries. ACS Energy Letters, 2 (6). pp. 1288-1295. ISSN 2380-8195

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Abstract

Long-lasting Li-Se cells with a Se/graphite platelet nanofiber (GPNF) composite is prepared for the first time, and it shows a reversible capacity of 489 and 384.7 mAh g(Se)(-1) after 200 and 350 charge/discharge cycles, respectively. It shows superior rate capability and low Se polarization even with a high Se (75 wt %) proportion. It also shows higher capacity and better cycling stability compared to conventional Se/carbon material composites (with graphene oxide (GO), reduced GO, and carbon nanotubes). The effectiveness of GPNFs as a conductive support and for inhibiting the shuttle and dissolution of polyselenides in the electrolyte is also confirmed by conducting atomic force microscopy studies. Nanoscale current maps of Se/GPNFs reveal the presence of homogeneously distributed high -current domains, which are retained even after the first discharge. In contrast, the pristine Se electrode is characterized by predominant low -current regions after the first discharge. The ability of GPNFs to enable the preparation of durable and easily processable Li-Se cells is demonstrated.

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IITH Creators:
IITH CreatorsORCiD
M, DeepaUNSPECIFIED
Item Type: Article
Uncontrolled Keywords: LITHIUM-SELENIUM BATTERIES; CATHODE MATERIAL; CARBON CATHODE; PERFORMANCE; SULFUR
Subjects: Chemistry > Electrochemistry
Others > Nanotechnology
Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 30 Jun 2017 05:35
Last Modified: 18 Oct 2017 07:00
URI: http://raiith.iith.ac.in/id/eprint/3313
Publisher URL: https://doi.org/10.1021/acsenergylett.7b00251
OA policy: http://www.sherpa.ac.uk/romeo/issn/2380-8195/
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