Synthesis and Characterisation of Anthracene Tagged Imidazolium Derivatives

Dudeja, Sahil (2016) Synthesis and Characterisation of Anthracene Tagged Imidazolium Derivatives. Masters thesis, Indian Institute of Technology Hyderabad.

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Abstract

Six new novel anthracene tagged imidazolium derivatives were successfully synthesized and characterized. [9,10-bis{(Nethoxycarbonylphenylimidazolium)methyl}anthracene] dichloride and [9,10-bis{(N-isopropylimidazolium)methyl}anthracene] dichloride were readily synthesized in very good yield by treating 9,10-bis(chloromethyl)anthracene with corresponding ethoxycarbonyl phenyl imidazole or N-isopropyimidazole, respectively. The anion exchange reaction of [9,10-bis{(N-ethoxycarbonylphenylimidazolium)methyl}anthracene] dichloride and [9,10-bis{(N-isopropylimidazolium)methyl}anthracene] dichloride with potassium hexafluorophosphate gave hexafluoro phosphate salt of [9,10-bis{(N-ethoxycarbonylphenylimidazolium)methyl}anthracene] and [9,10-bis{(N-iso propylimidazolium)methyl}anthracene] in excellent yields.

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IITH Creators:
IITH CreatorsORCiD
Item Type: Thesis (Masters)
Uncontrolled Keywords: dicationic heterophanes, cyclophane system, TD560
Subjects: ?? sub5.8 ??
Divisions: Department of Chemistry
Depositing User: Library Staff
Date Deposited: 30 Jun 2016 09:16
Last Modified: 30 Jun 2016 09:16
URI: http://raiith.iith.ac.in/id/eprint/2498
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