An Access to Fully Substituted β-Iodo N-Arylated Enamines via Dehydrogenative Iodoarylation of Vinylogous Carbamates Using Phenyliodine(III)diacetate(PIDA)

Chamuah, Ajay (2016) An Access to Fully Substituted β-Iodo N-Arylated Enamines via Dehydrogenative Iodoarylation of Vinylogous Carbamates Using Phenyliodine(III)diacetate(PIDA). Masters thesis, Indian Institute of Technology Hyderabad.

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Abstract

A novel and facile dehydrogenative iodoarylation of N-aryl vinylogous carbamates with hypervalent iodine (III) as the source of aryl and iodide has been developed. This protocol provides a valuable synthetic tool for the assembly of a wide range of β-iodo N-arylated enamines under mild conditions with functional group tolerance and scalability. This attractive route for the synthesis of β-iodo N-arylated enamines is of great importance due to the product versatile reactivity for further transformations.

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IITH Creators:
IITH CreatorsORCiD
Item Type: Thesis (Masters)
Uncontrolled Keywords: organic synthesis, N-aryl vinylogous carbamates, scalability, TD504
Subjects: ?? sub5.8 ??
Divisions: Department of Chemistry
Depositing User: Library Staff
Date Deposited: 05 May 2016 05:08
Last Modified: 05 May 2016 05:08
URI: http://raiith.iith.ac.in/id/eprint/2317
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