Thermal, optical and structural properties of disulfide and diselenide salts with weakly associated anions

Katam, S and Chatla, N B and G, Prabusankar (2015) Thermal, optical and structural properties of disulfide and diselenide salts with weakly associated anions. Journal of Molecular Structure, 1086. pp. 201-206. ISSN 0022-2860

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Abstract

The imidazole disulfide and diselenide dicataions were conveniently isolated for the first time by treating imidazole thione or imidazole selone with bismuth(III) triflate or copper perchlorate hexa-hydrate in very good yield. These new salts were characterized by elemental analysis, FT-IR, solid state UV-vis, thermogravimetric analysis and single crystal X-ray diffraction techniques. Interesting thermal properties and unusual bonding situations were observed for these dichalcogenide salts.

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IITH Creators:
IITH CreatorsORCiD
G, Prabusankarhttp://orcid.org/0000-0003-1772-135X
Item Type: Article
Uncontrolled Keywords: Disulfide; Diselenide; Thione; Selone; Imidazole
Subjects: Chemistry
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 25 Feb 2015 11:42
Last Modified: 12 Sep 2017 06:27
URI: http://raiith.iith.ac.in/id/eprint/1359
Publisher URL: https://doi.org/10.1016/j.molstruc.2015.01.016
OA policy: http://www.sherpa.ac.uk/romeo/issn/0022-2860/
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