A domino palladium catalysis: Synthesis of 7-methyl-5 H -dibenzo[ a, c ][7] annulen-5-ones

J, Krishna and A, Gopi Krishna Reddy and G, Satyanarayana (2013) A domino palladium catalysis: Synthesis of 7-methyl-5 H -dibenzo[ a, c ][7] annulen-5-ones. Synlett, 24 (8). pp. 967-972. ISSN 0936-5214

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A domino Pd-catalyzed reaction of 1-(2-bromophenyl)ethanones for the synthesis of novel 7-methyl-5H-dibenzo[a,c][7]annulen-5-ones, a carbon core structure present in colchicinoid natural products, is presented. The reaction is proposed to proceed via intermolecular homobiaryl coupling and intramolecular aldol condensation

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IITH Creators:
IITH CreatorsORCiD
G, SatyanarayanaUNSPECIFIED
Item Type: Article
Uncontrolled Keywords: 2-bromoacetophenones; aldol condensation; domino reaction; homobiaryl coupling; Pd catalysis
Subjects: ?? sub5.8 ??
Divisions: Department of Chemistry
Depositing User: Team Library
Date Deposited: 01 Dec 2014 07:21
Last Modified: 24 Sep 2015 10:25
URI: http://raiith.iith.ac.in/id/eprint/1079
Publisher URL: http://dx.doi.org/10.1055/s-0033-1338438
OA policy: http://www.sherpa.ac.uk/romeo/issn/0936-5214/
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